Prepared artificially since the earliest historical times and used until the nineteenth century, this warm white is very opaque, has outstanding brushing qualities and mixes well with every color on the artist's palette. As the name lead white suggests, it is a by-product of lead, and whatever the form of manufacture used, the purity of the color depends on the purity of the lead. Purifying processes greatly increase the cost of the product. White lead has always been one of the most important pigments in many painting techniques.
Its importance has been immeasurable, and is the only material that has been consistently used from ancient times until the present. The monopoly in lead white production was not broken until the nineteenth century, when zinc oxide became a competitor, and in the twentieth century, it has been almost completely replaced by titanium dioxide, which is superior to lead in some properties, and unlike zinc oxide, has the strong covering ability that lead white possesses. Since white in painting is the equivalent of light in nature, it has been essential to every aspect of painting: from flesh to skies, and so on.
In the Dutch and Old German process strips of lead rolled up into spirals were placed in closed earthenware jars containing acetic acid, and then pots were hen buried under tanner's bark or dung; the heat evolved by fermentation aids in the formation of white lead through an increase of carbonic acid. Very soon a thin coat of white coating forms. The white lead is then washed of and cleaned. White lead is extremely poisonous and must be handled with care.
White Lead in Vermeer's Painting
White has always played an important part in the art and craft of painting. The great part of pigments on a progressive scale of gray would fall into the medium dark to dark category. Only lead-tin yellow and lead-tin yellow are by themselves light pigments. In order to portray the light areas which are for indispensable to convey the sense of natural illumination, white must be added to heighten most of the darker pigments.
Vermeer, as all other painters of the time, used it extensively to lighten other colors and as the principal component used to depict white objects, such as ceramic jugs, white cloth (fig. 1) and the characteristic white-washed walls (fig. 2) seen in so many of his paintings.
A grainy texture can be seen on the surface of many of the lightest areas are caused by aggregates of white-lead particles. These lumpy aggregates that can "found in Vermeer's paintings have also been noted in several Frans Hal's paintings and are typical for the stack process of white lead production for which Holland was famous in the seventeenth century."Nicola Costaras, "A Study of the Materials and Techniques of Johannes Vermeer," in Vermeer Studies, ed. Ivan Gaskell (1998), 160.
Comprehensive Resources on Vermeer's Painting Techniques
BOON, J. and OBERTHALER, E., "Mechanical Weakness and Chemical Reactivity Observed in the Paint Structure and Surface of 'The Art of Painting'" in Vermeer: Die Malkunst - Spurensicherung an einem Meisterwerk, exh. cat., Kunsthistorisches Museum, Vienna 2010, 235–53 and 328–35.
COSTARAS, Nicola. "A Study of the Materials and Techniques of Johannes Vermeer." In Vermeer Studies, edited by Ivan Gaskell and Michiel Jonker, Studies in the History of Art 55, Center for Advanced Study in the Visual Arts, Symposium Papers XXXIII. Washington: National Gallery of Art & New Haven: Yale University Press, 1998, 145–167.
DELANEY, John K., Kathryn A. Dooley, Annelies van Loon, and Abbie Vandivere. "Mapping the Pigment Distribution of Vermeer's 'Girl with a Pearl Earring'." Heritage Science 8, no. 4 (January 7, 2020). Accessed May 2, 2022.
EASTAUGH, Nicholas, Valentine Walsh, Tracey Chaplin and Ruth Siddall. The Pigment Compendium 2017. Rev. ed. (e-version). London: The Pigmentum Project, 2016.
FINK, Daniel A. "Vermeer's Use of the Camera Obscura: A Comparative Study." The Art Bulletin 53 (1971).
GIEBE, Marlies. "Johannes Vermeers ‘Kupplerin': Restaurierung Und Maltechnische Befunde." In Uta Neidhardt and Marlies Giebe, eds., Johannes Vermeer: Bei der Kupplerin, 39–64. Exh. cat. Dresden: Michel Sandstein in association with Gemäldegalerie Alte Meister, Staatliche Kunstsammlungen, 2004.
GIFFORD, E. Melanie, Anikó Bezur, Andrea Guidi di Bagno, and Lisha Deming Glinsman. "The Making of a Luxury Image: Van Aelst's Painting Materials and Artistic Techniques." In Tanya Paul, James Clifton, Arthur K. Wheelock Jr., and Julie Hochstrasser, Elegance and Refinement: The Still-Life Paintings of Willem van Aelst, 80–84. Exh. cat. New York: Skira Rizzoli, 2012.
GIFFORD, M. "Painting Light: Recent Observations on Vermeer's Technique." In Vermeer Studies, edited by Ivan Gaskell and Michiel Jonker. Washington, D.C.: National Gallery of Art & New Haven and London: Yale University Press, 1998, 185–199.
GIFFORD, E. Melanie, and Lisha Deming Glinsman. "Collective Style and Personal Manner: Materials and Techniques of High-Life 'Genre Painting'." In Waiboer, Wheelock, and Ducos, Vermeer and the Masters of Genre Painting, 65–84, 270–74.
GIFFORD, E. Melanie, Dina Anchin, Alexandra Libby, Marjorie E. Wieseman, Kathryn A. Dooley, Lisha Deming Glinsman, John K. Delaney. "First Steps in Vermeer's Creative Process: New Findings from the National Gallery of Art," Journal of Historians of Netherlandish Art 14, no. 2 (Summer 2022).
GIFFORD, E. Melanie. "Fine Painting and Eloquent Imprecision: Gabriel Metsu's Painting Technique." In Adriaan E. Waiboe, Gabriel Metsu, 154–79. New Haven: Yale University Press in association with the National Gallery of Art, 2010."
GIFFORD, E. Melanie. "Lievens' Technique: ‘Wonders in Smeared Paint, Varnishes and Oils.'" In Jan Lievens: A Dutch Master Rediscovered, edited by Arthur K. Wheelock Jr., 41–53. Exh. cat. New Haven: Yale University Press in association with the National Gallery of Art, 2008.
GIFFORD, E. Melanie. "Material as Metaphor: Non-Conscious Thinking in Seventeenth Century Painting Practice." In Studying Old Master Paintings: Technology and Practice, edited by Marika Spring, 165–72. London: Archetype in association with The National Gallery, 2011.
GIFFORD, E. Melanie. "Painting Light: Recent Observations on Vermeer's Technique." In Vermeer Studies, edited by Gaskell and Jonker, 185–99.
GROEN, Karin M., Inez D. van der Werf, Klaas Jan van den Berg, and Jaap J. Boon. "Scientific Examination of Vermeer's 'Girl with a Pearl Earring'." In Vermeer Studies, edited by Ivan Gaskell and Michiel Jonker. Washington, D.C.: National Gallery of Art & New Haven and London: Yale University Press, 1998, 169–183.
KÜHN, Herman. "A Study of the Pigments and the Grounds used by Jan Vermeer." Reports and Studies in the History of Art. Washington: National Gallery of Art, 1968.
LAURENZE-LANDSBERG, Claudia. "Neutron-Autoradiography of Two Paintings by Jan Vermeer in the Gemäldegalerie Berlin." In Wolfgang Lefèvre, ed., Inside the Camera Obscura: Optics and Art under the Spell of the Projected Image, 213–25. Berlin: Max-Planck Institute for the History of Science, 2007.
LEVY-HALM, Koos. "Where Did Vermeer Buy His Painting Materials? Theory and Practice." In Gaskell and Jonker, Vermeer Studies, 137–43.
LIBBY, Alexandra, E. Melanie Gifford, Dina Anchin, Marjorie E. Wieseman, Kathryn A. Dooley, Lisha Deming Glinsman, John K. Delaney. "Experimentation and Innovation in Vermeer's 'Girl with the Red Hat': New Findings from the National Gallery of Art," Journal of Historians of Netherlandish Art 14, no. 2 (Summer 2022).
LIEDTKE, Walter A., Richard C. Johnson, and Don H. Johnson. "Canvas Matches in Vermeer: A Case Study in the Computer Analysis of Fabric Supports." Metropolitan Museum Journal 47 (2012): 101–8.
LOON, Annelies van, Abbie Vandivere, John K. Delaney, Kathryn A. Dooley, Steven De Meyer, Frederik Vanmeert, Victor Gonzalez, Koen Janssens, Emilien Leonhardt, Ralph Haswell, Suzan de Groot, Paolo D'Imporzano and Gareth R. Davies. "Beauty is Skin Deep: The Skin Tones of Vermeer's Girl with a Pearl Earring." Heritage Science 7, no. 102 (December 11, 2019). Accessed May 2, 2022.
LOON, Annelies van, Alessa A. Gambardella, Victor Gonzalez, Marine Cotte, Wout De Nolf, Katrien Keune, Emilien Leonhardt, Suzan de Groot, Art Ness Proaño Gaibor, and Abbie Vandivere. "Out of the Blue: Vermeer's Use of Ultramarine in Girl with a Pearl Earring." Heritage Science 8, no. 25 (February 28, 2020). Accessed May 2, 2022.
NEIDHART, Uta, and Marlies GIEBE, with essays by Albert Blankert, Chrisitne Klose, Johann Koller, Annalise Mayer-Meintsschel et al. Johannes Vermeer 'Bei der Kupplerin,' exh. cat. Dresden, 2004.
PEETERS, Natasja. "The Painter's Apprentice in Fifteenth and Sixteenth Century Antwerp: An Analysis of the Archival Sources." Mélanges de l'École française de Rome: Italie et Méditerranée modernes et contemporaines, nos. 131–2 (2019), 221–27, https://doi.org/10.4000/mefrim.6461.
POTTASCH, Carol. "Underdrawings in the Paintings of Frans van Mieris." In Quentin Buvelot, Frans van Mieris 1635–1681, 62–68. Exh. cat. Zwolle: Waanders 2005.
OBERTHALER, E., J. Boon, S. Stanek, and M. Griesser. "'The Art of Painting' by Johannes Vermeer. History of Treatments and Observations on the Present Condition." In Vermeer, Die Malkunst: Spurensicherung an einem Meisterwerk, exh. cat. Vienna: Kunsthistorisches Museum, 2010, 215–234 and 322–327. See especially illustrations 49 and 50.
SHELDON, L., and N. Costaras. "Johannes Vermeer's 'Young Woman Seated at a Virginal'." The Burlington Magazine 148 (February 2006): 89–97.
SIVEL, Valerie, Joris Dik, Paul Alkemade, Libby Sheldon, and Henny Zandbergen. "The Cloak of 'Young Woman Seated at a Virginal': Vermeer, or a Later Hand?" ArtMatters: Netherlands Technical Studies in Art 4 (2007): 90–96.
VANDIVERE, Abbie, ed., "The Girl in the Spotlight: A Technical Re-Examination of Vermeer's 'Girl with a Pearl Earring'." Special Collection, Heritage Science 7–8 (2019–20). Accessed May 2, 2022.
VERSLYPE, Ige. "The Restoration of 'Woman in Blue Reading a Letter' by Johannes Vermeer." The Rijksmuseum Bulletin 60, no. 1 (2012): 2–19.
WALD, Robert. "'The Art of Painting': Observations on Approach and Technique." In Sabine Haag, Elke Oberthaler, and Sabine Pénot, Vermeer, Die Malkunst: Spurensicherung an einem Meisterwerk, 312–27. Exh. cat. St. Pölten: Residenz in association with Kunsthistorisches Museum, Vienna, 2010.
WALLERT, Arie. "The Materials and Methods of Michiel Sweerts's Paintings." In Jansen and Sutton, Michiel Sweerts, 37–47.
WADUM, Jørgen, René Hoppenbrouwers, and Luuk Struick van der Loeff. Vermeer Illuminated: Conservation, Restoration and Research: A Report on the Restoration of the View of Delft and the Girl with a Pearl Earring by Johannes Vermeer. Wormer: V+K in association with the Royal Cabinet of Paintings Mauritshuis, The Hague, 1994.
WADUM, Jørgen. "Contours of Vermeer." In Vermeer Studies. New Haven and London, 1998, 201–223.
WIESEMAN, Marjorie E. "Acquisition or Inheritance? Material Goods in Paintings by Vermeer and His Contemporaries." In Waiboer, Wheelock, and Ducos, Vermeer and the Masters of Genre Painting, 50–63.
WIESEMAN, Marjorie E., Alexandra Libby, E. Melanie Gifford, Dina Anchin. "Vermeer's Studio and the 'Girl with a Flute': New Findings from the National Gallery of Art," Journal of Historians of Netherlandish Art 14, no. 2 (Summer 2022).